Complexes of the “proton sponge” 1,8-bis(dimethylamino)naphthalene (DMAN): Part 5. The structure at 100 K of [DMANH]+·[dihydrogen hemimellitate]− hemihydrate
✍ Scribed by Mia L. Raves; Jan A. Kanters; Eugenius Grech
- Book ID
- 107806817
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 661 KB
- Volume
- 271
- Category
- Article
- ISSN
- 0022-2860
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Low-temperature (120 K) studies of the structure of the DMAN Á DCI adduct indicate that in symmetrical [NHN] hydrogen bridge of 2.571 (1) A ˚length (2.579(2) A ˚at room temperature) there is a disorder of the H-atom occupying two positions at nitrogen atoms with a distance of 0.94(3) A ˚. The compa
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