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Thermionic ionization detection of halogenated compounds using supercritical fluid chromatography

✍ Scribed by Raymond K. Jew; Bruce E. Richter

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
362 KB
Volume
5
Category
Article
ISSN
1040-7685

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✦ Synopsis

Abstract

A thermionic ionization detector utilizing the TID‐1‐N~2~ mode for the analysis of chlorinated compounds was evaluated for use with supercritical fluid chromatography (SFC). A nitrogen atmosphere was employed in the detection zone to give electron capture detector (ECD)‐like responses. Optimum conditions allowed detection of halogenated compounds in the low picogram range with good base line stability during density programming. Selectivity over aliphatics and aromatics ranged between 10^4^ to 10^5^.

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