## Abstract A method for determining total conjugated dienes in petroleum products, such as catalytic or thermal cracking fractions, using supercritical fluid chromatography (SFC) is presented. The separation is carried out in one or two silica columns and with CO~2~ as mobile phase. The conditions
Supercritical fluid chromatography of petroleum products using flameless sulfur chemiluminescence detection
✍ Scribed by Shearer, Randy L. ;Skelton, Ron J.
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 429 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0935-6304
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✦ Synopsis
Abstract
Supercritical fluid chromatography using flameless sulfur chemiluminescence detection has been investigated for the analysis of sulfur compounds in petroleum products. The chromatography and detection system was easy to implement and exhibited good precision, linearity, selectivity, and sensitivity. A minimum detectable limit of 0.3 pg sulfur/s was obtained, and response to sulfur in different sulfur species was nearly equimolar.
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