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Thermal transcarboxylation reactions, II. The study of carboxyl group exchange in the course of ketone formation

✍ Scribed by J. Szammer; A. Szabolcs; L. Noszko

Publisher: John Wiley and Sons
Year: 1974
Tongue: French
Weight: 309 KB
Volume: 10
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.2590100312

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✦ Synopsis

Abstract

The course of carboxyl group exchange in the thermal decomposition of a mixture of disodium adipate and pimelate has been studied using ^14^C‐labelled compounds. The exchange data obtained from the residual acide and ketone formed point to two different incorporation processes. This phenomenon can be well interpreted by presuming the presence of a malonta type intermediate formed in the decomposition process.

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