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Thermal transcarboxylation reactions VIII. A study on the process of anomalous carboxyl group – CO2 exchange

✍ Scribed by J. Szammer; A. Szabolcs

Publisher
John Wiley and Sons
Year
1976
Tongue
French
Weight
301 KB
Volume
12
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

The anomalous course of ^14^CO~2~ incorporation observed in the thermal transformation of disodium adipate was studied. It has been established that the thermal transformation of butane‐1,1,4‐tricarboxylic acid trisodium salt is accompanied by intramolecular 1‐4 transfer of carboxyl groups. The results of ^14^C incorporation and carboxyl group exchange suggest that disodium adipate α‐carbanion is present and participates in the reaction in cyclic form.

📜 SIMILAR VOLUMES

Thermal transcarboxylation reactions, II
Thermal transcarboxylation reactions, II. The study of carboxyl group exchange in the course of ketone formation
✍ J. Szammer; A. Szabolcs; L. Noszko 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 French ⚖ 309 KB

## Abstract The course of carboxyl group exchange in the thermal decomposition of a mixture of disodium adipate and pimelate has been studied using ^14^C‐labelled compounds. The exchange data obtained from the residual acide and ketone formed point to two different incorporation processes. This phe