✦ LIBER ✦

Carboxyl group -CO2 exchange in the thermal decomposition of aliphatic dicarboxylic acid salts

✍ Scribed by A. Szabolcs; J. Szammer

Publisher: John Wiley and Sons
Year: 1974
Tongue: French
Weight: 244 KB
Volume: 10
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.2590100113

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✦ Synopsis

Abstract

The exchange reaction of carboxyl groups with carbon dioxide has been studied in thermal decomposition of aliphatic dicarboxylic acid disodium salts. It has been found that exchange takes place under given experimental conditions. In some cases the process results in considerable exchange even in lower conversion ranges therefore it is of significance in the field of isotopes techniques.

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