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Thermal rearrangement of 2-oxabicyclo[2.2.2]oct-5-eno-3-carboxylic acids

โœ Scribed by O. Achmatowicz Jr.; J. Jurczak; J.S. Pyrek


Book ID
103399276
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
292 KB
Volume
32
Category
Article
ISSN
0040-4020

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irradiation of 8-oxabicyclo[3.2.l]oct-6-en-2-ones results in a 1 ,Sacyl rearrangement. The initial photoproduct undergoes a subsequent reaction involving hydrogen transfer followed by intramolecular cycloaddition of a ketene intermediate.