Reactions of ethyl 2-acetyl-2-azabicyclo[2.2.1]hept-5-ene-3-carboxylate and 4-acetylamino-2-oxabicyclo[3.3.0]oct-7-en-3-one with some electrophiles
β Scribed by Hursthouse, Michael B.; Malik, K. M. Abdul; Hibbs, David E.; Roberts, Stanley M.; Seago, Amanda J. H.; ?ik, Vladimir; Storer, Richard
- Book ID
- 115481847
- Publisher
- Royal Society of Chemistry
- Year
- 1995
- Weight
- 1019 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1472-7781
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π SIMILAR VOLUMES
Allylic oxidation of 4-allyl-1-dimethyl-t-butylsilylazetidin-2ones (5,7) gave the 4-(l-hydroxyprop-2-ene-1-yl) derivatives (6,8). Radical benzoyloxylation of the silylated 8-oxo-7-azabicyclo[4.2.O]oct-3ene (18) provided four allylic monobenzoates. Progression of ( ) and ( ) afforded, respectively,
## Abstract Dehydrochlorination of chlorinated 5βhydroxyβ2βoxabicyclo[3.2.0]heptanβ4βones, 3aβc, which were obtained from the photo[2+2]cycloadditions between 4βhydroxyβ3(2__H__)βfuranone 1 and chloroethylenes, with triethylamine gave 2βethenylβ3(2__H__)βfuranones 4a,b or 2β(2βcyanoethyl)β3(2__H__)