ChemInform Abstract: Reactions of Ethyl 2-Acetyl-2-azabicyclo(2.2.1)hept-5-ene-3- carboxylate and 4-Acetylamino-2-oxabicyclo(3.3.0)oct-7-en-3-one with Some Electrophiles.
โ Scribed by M. B. HURSTHOUSE; K. M. A. MALIK; D. E. HIBBS; S. M. ROBERTS; A. J. H. SEAGO; V. SIK; R. STORER
- Book ID
- 112025626
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
Allylic oxidation of 4-allyl-1-dimethyl-t-butylsilylazetidin-2ones (5,7) gave the 4-(l-hydroxyprop-2-ene-1-yl) derivatives (6,8). Radical benzoyloxylation of the silylated 8-oxo-7-azabicyclo[4.2.O]oct-3ene (18) provided four allylic monobenzoates. Progression of ( ) and ( ) afforded, respectively,
## Abstract Dehydrochlorination of chlorinated 5โhydroxyโ2โoxabicyclo[3.2.0]heptanโ4โones, 3aโc, which were obtained from the photo[2+2]cycloadditions between 4โhydroxyโ3(2__H__)โfuranone 1 and chloroethylenes, with triethylamine gave 2โethenylโ3(2__H__)โfuranones 4a,b or 2โ(2โcyanoethyl)โ3(2__H__)