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Thermally induced cyclobutyl-cyclopropylcarbinyl-type rearrangement of 2-oxabicyclo[4.2.0]octan-3-ones

โœ Scribed by Kakiuchi, Kiyomi; Tobe, Yoshito; Odaira, Yoshinobu


Book ID
126230514
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
439 KB
Volume
45
Category
Article
ISSN
0022-3263

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Unprecedented Grob-type fragmentation of
โœ Marzia De Giacomo; Rinaldo Marini Bettolo; Rita Scarpelli ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 123 KB

The unprecedented Grob-t)pc l'ragmentations of 5-dioxolan-bic)clol4.2.0loctan-2-oncs l into 3-(methoxycarlxmylmethyl)cyclohcxanones 2 arc described. This fragmentation, in combination with the allene photoannelation used to prcxluce compounds I. might constitute an indirect way for achieving conjuga