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Thermal reaction of hydrogen–butene-2-cis mixtures at 500°C: Hydrogenation, hydrogenolysis, and thermal reaction of the olefin

✍ Scribed by C. Collongues; C. Richard; R. Martin

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
667 KB
Volume
15
Category
Article
ISSN
0538-8066

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✦ Synopsis

The thermal reaction of hydrogen-butene-24s mixtures has been studied in a static system at low extent of reaction around 500°C. Hydrogen does not affect the thermal reaction itself of the olefin, hut gives rise to new stoichiometries of hydrogenolysis and hydrogenation, which are specified

The reaction is described in terms of a molecular and free-radical mechanism. It is shown that the key process for the hydrogenolysis-hydrogenation reaction is

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