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The thermal reactions of ethylene at 500°C in the presence and absence of small quantities of oxygen

✍ Scribed by M. H. Back; R. Martin

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
721 KB
Volume
11
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Initial rates of formation of primary products have been measured in the pyrolysis of ethylene at 500°C, and a mechanism for the reaction is proposed based on the isomerization of the n−hexyl radical. Additions of oxygen in amounts less than 0.1% markedly increased the rate of formation of all products, but oxygen was not completely consumed in the reaction. It is shown that secondary initiation processes are important at very low conversions, and butene‐1 is the most reactive product. Bimolecular reactions between olefins and with oxygen are important steps in the mechanism.

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