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Thermal oxidation of blends of poly(vinyl methyl ether) and modified polystyrenes

✍ Scribed by Hyunkil Park; Eli M. Pearce; W. H. Starnes Jr.; T. K. Kwei


Book ID
105337486
Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
474 KB
Volume
28
Category
Article
ISSN
0887-624X

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✦ Synopsis


Abstract

Thermal oxidation of blends of poly(vinyl methyl ether) and styrene copolymers containing hydroxyl groups as hydrogen‐bond donors was studied. The hydrogen‐bonding interaction provide for improved miscibility between the component polymers and more extensive crosspropagation/cross‐termination reactions. In addition to their contribution to improved miscibility, phenol groups in the copolymers exhibited apparent antioxidant and prooxidant effects.


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This article presents thermal diffusivity ( D) measurements by flash radiometry for the polymer blend of polystyrene (PS) and poly(vinyl methyl ether) (PVME) with lower critical solution temperature (LCST) phase diagram. Dependence of D on PS content measured at 100ЊC coincides a phase diagram deter

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