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Rheology and phase separation in polystyrene/poly(vinyl methyl ether) blends

✍ Scribed by A. Ajji; L. Choplin; R. E. Prud'homme

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
494 KB
Volume
26
Category
Article
ISSN
0887-6266

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## Abstract We have investigated the fluorescence emission spectra of pyrene and anthracene dyes covalently bonded to polystyrene (PS) upon phase separation from poly(vinyl methyl ether) (PVME). The specific chemical structure of the fluorescent labels is found to affect the measured phase separati

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Polystyrene (PS) samples carrying terminal or in-chain nitroxide spin labels have been blended with poly(vinyl methyl ether) (PVME) in varying proportions and their electron spin resonance (ESR) spectra recorded over a range of temperatures. The spectra are mainly of the slow-motion type but reΓ‘ect

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The effect of phase-separated morphology on the rheological properties of polystyrene/poly(vinyl methyl ether) (PS/PVME) blend was investigated by optical microscopy (OM), light scattering (LS) method, and rheology. The blend had a lower critical solution temperature (LCST) of 112Β°C obtained by turb