Thermal decomposition of benzoyl azide and diazoacetone in the gas phase
β Scribed by V. G. Prokudin; A. M. Sipyagin; V. G. Kartsev; S. A. Vozchikova
- Book ID
- 112448698
- Publisher
- Springer
- Year
- 1988
- Tongue
- English
- Weight
- 332 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1573-9171
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Gas phase decomposition of tetranitromethane, hexanitroethane, chtoro-, bromo-, iodo-trinitromethane and dichlorodinitromethane has been studied over a temperature range from 100 Β° to 160Β°C using a manometric method, The reactions were found to be homogeneous and first order. The rates were independ
## Abstract The cyclic sulfenic ester 1,2βoxathiolane (**1**) decomposes thermally (400 β 450 K) exclusively to give acrolein (**3**) __via__ 3βmercaptopropanal (**2**) by loss of hydrogen sulfide. Isotopic labelling experiments reveal the presence of a 1,2βoxathiolaneβthietane 1βoxide equilibrium