## Abstract The cyclic sulfenic ester 1,2‐oxathiolane (**1**) decomposes thermally (400 – 450 K) exclusively to give acrolein (**3**) __via__ 3‐mercaptopropanal (**2**) by loss of hydrogen sulfide. Isotopic labelling experiments reveal the presence of a 1,2‐oxathiolane‐thietane 1‐oxide equilibrium
✦ LIBER ✦
Thermal decomposition of 1,1-dinitroalkanes in the gas-phase
✍ Scribed by G. M. Nazin; G. B. Manelis; F. I. Dubovitskii
- Book ID
- 112431569
- Publisher
- Springer
- Year
- 1968
- Tongue
- English
- Weight
- 202 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1573-9171
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