## Abstract The cyclic sulfenic ester 1,2‐oxathiolane (**1**) decomposes thermally (400 – 450 K) exclusively to give acrolein (**3**) __via__ 3‐mercaptopropanal (**2**) by loss of hydrogen sulfide. Isotopic labelling experiments reveal the presence of a 1,2‐oxathiolane‐thietane 1‐oxide equilibrium
Radical-sensitized thermal decomposition of 1,3-dioxolane in the gas phase
✍ Scribed by E. Fernández-Sánchez; J.A. García-Domínguez; B. De la Iglesia-Gayá
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 1013 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0165-2370
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The gas‐phase thermal decomposition of 5‐ethyl‐1‐pyrroline has been studied in the temperature range 721–786 K. The decomposition appears to proceed by two pathways, one a radical route yielding pyrrole, ethylene and ethane as major products, and the other a molecular hydrogen eliminati
Gas phase decomposition of tetranitromethane, hexanitroethane, chtoro-, bromo-, iodo-trinitromethane and dichlorodinitromethane has been studied over a temperature range from 100 ° to 160°C using a manometric method, The reactions were found to be homogeneous and first order. The rates were independ
The photolysis of perfluoroglutaryl dichloride was investigated in the gas phase with the light of the full arc of a high pressure mercury lamp. At high intensities and conversions the main products are CO and ClCF&F,CF&l, and the ratio CO/Cl(CF,),Cl is 2. However, in runs with attenuated light and
## Abstract The kinetics of the gas‐phase thermal isomerization between __trans__‐ and __cis__‐1,2‐bis(trifluoromethyl)‐1,2,3,3‐tetrafluorocyclopropane as well as their decomposition to __trans__‐ and __cis__‐perfluoro‐2‐butene, respectively, and CF~2~, was studied in the temperature range of 473–5