𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Thermal decomposition of gem-trinitroalkanes in the gas phase

✍ Scribed by G. M. Nazin; G. B. Manelis; F. I. Dubovitskii


Book ID
112434117
Publisher
Springer
Year
1968
Tongue
English
Weight
228 KB
Volume
17
Category
Article
ISSN
1573-9171

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Thermal decomposition of some polynitroc
✍ G.M. Nazin; G.B. Manelis; G.N. Nechiporenko; F.I. Dubovitsky πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 English βš– 372 KB

Gas phase decomposition of tetranitromethane, hexanitroethane, chtoro-, bromo-, iodo-trinitromethane and dichlorodinitromethane has been studied over a temperature range from 100 Β° to 160Β°C using a manometric method, The reactions were found to be homogeneous and first order. The rates were independ

Thermal Decomposition of 1,2-Oxathiolane
✍ Carlsen, Lars ;Egsgaard, Helge πŸ“‚ Article πŸ“… 1984 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 293 KB πŸ‘ 2 views

## Abstract The cyclic sulfenic ester 1,2‐oxathiolane (**1**) decomposes thermally (400 – 450 K) exclusively to give acrolein (**3**) __via__ 3‐mercaptopropanal (**2**) by loss of hydrogen sulfide. Isotopic labelling experiments reveal the presence of a 1,2‐oxathiolane‐thietane 1‐oxide equilibrium