𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Thermal decomposition behavior of naphthalene-labeled polyethylene

✍ Scribed by Xigao Jin; Yi Shi; Li Yao; Liusheng Chen; Jianrong Feng; Mitchell A. Winnik

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
419 KB
Volume
34
Category
Article
ISSN
0887-624X

No coin nor oath required. For personal study only.

✦ Synopsis

Pyrolysis-GC/mass spectrometry experiments reveal that naphthalene groups attached to maleated polyethylene as the 1-naphthylethyl ester are stable for relatively long periods of time a t 170Β°C. Decomposition can be detected for samples heated for 2.0 min a t 2OO0C, but even a t t h a t temperature, the extent of decomposition is very small. At higher temperatures, two of the decomposition products from the labeled polymer are readily understood: 1-vinylnaphthalene and 1-naphthylethanol can form by reactions that are well-precedented in the organic chemistry literature. At 200Β°C, only naphthalene is formed, which requires scission of the bond between the naphthyl ring and the C, carbon of the ethyl group. We suggest two possible pathways for this reaction. 0 1996

πŸ“œ SIMILAR VOLUMES

Thermal decomposition of biphenyl and na
Thermal decomposition of biphenyl and naphthalene in a flow system
✍ J. Lahaye; H.B. Palmer; R.K. Sharma πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 English βš– 159 KB

THIS note briefly reports some experiments on the pyrolysis of biphenyl and naphthalene, using a hot flow reactor of the type used in some previous studies of hydrocarbon decomposition."-8) As there is little literature on the decomposition of biphenyl(4) or naphthalene,(s\* 6) in the gas phase, it

Thermal decomposition of amide and imide
Thermal decomposition of amide and imide derivatives of maleated polyethylene
✍ Liyan Huang; Yi Shi; Liusheng Chen; Xigao Jin; Ronghua Liu; Mitchell A. Winnik; πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 215 KB

The thermal decomposition behavior of six derivatives of maleated polyethylene was investigated by high-resolution pyrolysis gas chromatography-mass spectrometry. The results revealed that substituents attached to maleated polyethylene as amides formed from secondary amines were significantly less s

Synthesis and thermal decomposition of 1
Synthesis and thermal decomposition of 15N-labelled NTO
✍ Leimin Fan; Chhabil Dass; Theodore J. Burkey πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 French βš– 415 KB πŸ‘ 1 views

5-Nitro-2,4-dihydro-3H-l,2,4-triazol-3-one (NTO) has been synthesized in good yield with 15N at the 1 and 2 positions. The N-H coupling provides unequivocal assignments for I H and 15N NMR spectra and the acidic proton. The products of thermal decomposition at 270 O C were identified spectroscopical

Thermal behavior and properties of napht
Thermal behavior and properties of naphthalene containing bismaleimide–triazine resins
✍ Hann-Jang Hwang; Chun-Shan Wang πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 214 KB πŸ‘ 2 views

A series of bismaleimidertriazine (BT) resins were prepared from various dicyanate esters and 2,7-bis(4-maleimidophenoxy)naphthalene (BMPN), which contains a naphthalene group and an aryl ether linkage in the backbone. Their curing behaviors were characterized by differential scanning calorimetry. T

Thermal decomposition behavior of miscib
Thermal decomposition behavior of miscible cellulose/synthetic polymer blends
✍ Noboru Nishioka; Shinji Hamabe; Tomoaki Murakami; Tomoya Kitagawa πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 152 KB πŸ‘ 2 views

The thermal decomposition behavior of the miscible cellulosic blends cellulose(Cell)/poly( N-vinyl-2-pyrrolidone) (PVP), Cell/poly(ethylene glycol) (PEG), and Cell/poly(vinyl alcohol) (PVA) was investigated by thermogravimetry. The thermal stability of Cell in the Cell/PVP blends decreased but that