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Thermal behavior of exo-5-substituted bicyclo[2.1.0] pentanes

✍ Scribed by J.J. Tufariello; A.C. Bayer

Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
202 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis

Recent investigations of the solvolytic behavior of s-5-bicyclo[2.1.0]pentyl derivatives (I) have uncovered a remarkable reactivity (1). Thus,

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✍ Klaus Fellenbergger; Ulrich SchΓΆllkopf πŸ“‚ Article πŸ“… 1972 πŸ› Elsevier Science 🌐 French βš– 201 KB

Wle friiher berlchtet 1,2) nlmmt die Solvolysegeschwlndlgkelt von exo-Blcyclo-(n, l,O)-alkyltosylaten (I) In der Folge n = 5.4.3 ab, wobel der Effekt helm Ubergang von n = 4 nach n = 3 besonders ausgeprlgt 1st (vgl. Tab. 1). Dies 1st ver-st&ndllch, well die mit der Ionlsatlon verbundene Dlsrotatlon

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