Recent investigations of the solvolytic behavior of s-5-bicyclo[2.1.0]pentyl derivatives (I) have uncovered a remarkable reactivity (1). Thus,
Transition metal catalyzed isomerization of substituted bicyclo[2.1.0] Pentanes
โ Scribed by Kenneth B. Wiberg; K.C. Bishop III
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 194 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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We wish to report the first example of a zinc-catalyzed rearrangement of the bicycle [P.l.O]pentane ring system. Namely, the rearrangement of I-Phenylbicyclo[2.1.O]pentane(b) with a catalytic amount of zinc iodide in benzene (2 hr, 60') to give as the sole product 3-phenylcyclopentene(2a).
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