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Thermal and photochemical cationic polymerisations induced by AgPF6in the presence of free radical initiators

✍ Scribed by Firas A. M. Abdul-Rasoul; Anthony Ledwith; Yusuf Yagci

Book ID
104702118
Publisher
Springer
Year
1978
Tongue
English
Weight
244 KB
Volume
1
Category
Article
ISSN
0170-0839

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Free radical initiation mechanisms in the polymerisation of diethyl fumarate and diethyl maleate studied by the nitroxide trapping technique
✍ W. Ken Busfield; Ian D. Jenkins; Kirstin Heiland πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 580 KB

The radical trapping technique employing the stable nitroxide 1 as a scavenger has been used to study the reaction of t-butoxyl radicals with diethyl fumarate and with diethyl maleate. The major pathway with both monomers is hydrogen abstraction from the ester alkyl groups by t-butoxyl radicals. The