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Radical-induced ionic polymerization in the presence of maleic anhydride. I. Mechanism of polymerization of maleic anhydride by radical initiators

✍ Scribed by Y. Nakayama; K. Hayashi; S. Okamura


Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
834 KB
Volume
18
Category
Article
ISSN
0021-8995

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Radical-induced ionic polymerization in
✍ Y. Nakayama; K. Kondo; K. Takakura; K. Hayashi; S. Okamura πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 332 KB πŸ‘ 2 views

The cationic polymerization of 1,Zbutylene oxide initiated by radical catalysts has been investigated in detail in the presence of maleic anhydride. The active species of this ionic polymerization was thought to be a conjugated radical of poly(maleic anhydride).

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✍ T. Ouchi; T. Azuma πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 English βš– 240 KB

The photopolymerization of maleic anhydride (Manh) was carried out in the presence of 2,4,8,10-tetraoxaspiro [5,5]undecane (TU) at 40' in vacuo without initiator to give the hygroscopic oligomer of Manh having a TU unit as each of the end-groups and a small amount of the cyclic dimer of Manh. The in