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Changes in the Spin State and Reactivity of Cytochrome c Induced by Photochemically Generated Singlet Oxygen and Free Radicals

✍ Scribed by Estevam, Mauren L. (author);Nascimento, Otaciro R. (author);Baptista, Mauricio S. (author);Di Mascio, Paolo (author);Prado, Fernanda M. (author);Faljoni-Alario, Adelaide (author);Do Rosario Zucchi, Maria (author);Nantes, Iseli L. (author)


Book ID
121795743
Publisher
The American Society for Biochemistry and Molecular Biology
Year
2004
Tongue
English
Weight
829 KB
Volume
279
Category
Article
ISSN
0021-9258

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Two-State Reactivity in the Rebound Step
✍ Nathan Harris; Shimrit Cohen; Michael Filatov; FranΓ§ois Ogliaro; Sason Shaik πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 119 KB πŸ‘ 1 views

Alkane hydroxylation [1] by cytochrome P-450 poses tantalizing mechanistic questions. The consensus rebound mechanism, Scheme 1, [2] involves hydrogen abstraction from the Scheme 1. Schematic representation of the rebound mechanism.