Additions and Corrections - Photochemical Formation of Free Radicals from Olefinic and Acetylenic Compounds in the Frozen State as Studied by Electron Spin Resonance.
✍ Scribed by Volman, D.; Maas, K.; Wolstenholme, J.
- Book ID
- 126172791
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 72 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0002-7863
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## Abstract Various free radicals formed during UV.‐irradiation of aliphatic dicarboxylic acids in aqueous and methanolic solution are identified by ESR.‐spectroscopy. Their structures point to α‐cleavage and photoreduction as the dominant primary photochemical decay processes. The relative contrib
## Abstract During UV.‐irradiation of aliphatic carboxylic acids and esters in aqueous and nonaqueous solutions various alkyl and acyl type radicals derived from parent compounds and solvents have been observed by ESR.‐spectroscopy. The structures of the radicals point to α‐cleavage, β‐dehalogenati