𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Thermal and high pressure intramolecular Diels–Alder reaction of vinylsulfonamides

✍ Scribed by Rogachev, Victor O; Metz, Peter


Book ID
109946028
Publisher
Nature Publishing Group
Year
2006
Tongue
English
Weight
442 KB
Volume
1
Category
Article
ISSN
1750-2799

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Preparation of enantiopure sultams by in
✍ Viktor O. Rogatchov; Heiko Bernsmann; Pia Schwab; Roland Fröhlich; Birgit Wibbel 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 102 KB

Enantiomerically pure dand g-sultams have been prepared by intramolecular [4+2] cycloaddition of N-1-phenylethyl substituted vinylsulfonamides with purely thermal activation and under high pressure. An optimized procedure for reductive debenzylation of the resultant d-sultams is also reported.

High pressure intramolecular Diels-Alder
✍ Brian A. Keay; Peter W. Dibble 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 147 KB

A variety of substituted furans a-6J undergo the intramolecular Die&Alder reaction at high pressure (12.5 kbar) to provide oxatricyclo adducts Q-12) within 24 hours at room temperature.