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Preparation of Enantiopure Sultams by Intramolecular Diels—Alder Reaction of Furan-Containing Vinylsulfonamides.

✍ Scribed by Viktor O. Rogatchov; Heiko Bernsmann; Pia Schwab; Roland Froehlich; Birgit Wibbeling; Peter Metz

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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✍ Grazia Cafeo; Marco Giannetto; Franz H. Kohnke; Giovanna L. La Torre; Melchiorre 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 363 KB 👁 1 views

The simple chemical modification by Diels ± Alder reactions of the cyclic hexamer of furan and acetone, utilising two readily accessible dienophiles, benzyne and dimethylacetylenedicarboxylate (DMAD), is described. The studies have explored the ease with which different furan units within the macroc