𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Theory of proton-transfer reactions. On the solvent dependence of the kinetic isotope effect

✍ Scribed by J. Sühnel; K. Gustav

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
375 KB
Volume
88
Category
Article
ISSN
0301-0104

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetic isotope effects on the Menshutki
Kinetic isotope effects on the Menshutkin reaction: Theory versus experiment
✍ E. Gawlita; A. Szylhabel-Godala; P. Paneth 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 652 KB

Nitrogen, carbon and secondary deuterium kinetic isotope effects were calculated for the Menshutkin reaction between methyl iodide and para-substituted aromatic N,N-dimethylamines using quantum mechanical methods. Different semiempirical Hamiltonians and continuum solvent models were evaluated on th

Temperature Dependence of the Primary Ki
Temperature Dependence of the Primary Kinetic Isotope Effect in Hydride Transfer Reactions with NAD+and NADH Models
✍ Vladimir Leskovac; Svetlana Trivić; Emilija Nikolić-Djorić 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 160 KB

N 1 -(2,6-dichlorobenzyl)-1,4-( 1 H 2 )dihydronicotinamide and N 1 -(2,6-dichlorobenzyl)-1,4-( 1 H, 2 H)dihydronicotinamide were oxidized with nitrosobenzene (NOB), 2,6-dichloroindophenol (DCPIP), 2,4,6-trinitrobenzenesulfonic acid (TNBS), 10-methyl-acridinium ion (MAI), and 10-methyl-9-phenyl-acrid

Hydrogen/deuterium isotope effects on th
Hydrogen/deuterium isotope effects on the excited-state proton transfer kinetics of 3-hydroxyflavone
✍ A.J.G. Strandjord; P.F. Barbara 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 631 KB

The static and transient fluorescence spectroscopy of 3-hydroxyflavone, 3HF, has been investigated as a function of deuteration of the 3-hydroxy group and the solvent. Small H/D isotope effects are observed for at least two of the simple rate constants for the excited-state dynamics. The isotope eff