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Theoretical study of the kinetic isotope effect in proton-transfer reactions. Influence of the interaction potential of reactants on the kinetic isotope effect

✍ Scribed by J. Sühnel; K. Gustav

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
728 KB
Volume
70
Category
Article
ISSN
0301-0104

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✍ A.J.G. Strandjord; P.F. Barbara 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 631 KB

The static and transient fluorescence spectroscopy of 3-hydroxyflavone, 3HF, has been investigated as a function of deuteration of the 3-hydroxy group and the solvent. Small H/D isotope effects are observed for at least two of the simple rate constants for the excited-state dynamics. The isotope eff