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Theory of Fluorescence Depolarization by Anisotropic Rotational Diffusion

โœ Scribed by Chuang, T. J.

Book ID
120506427
Publisher
American Institute of Physics
Year
1972
Tongue
English
Weight
564 KB
Volume
57
Category
Article
ISSN
0021-9606

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Existing derivations of the time-dependent fluorescence anisotropy of an asymmetric molecule constitute a straightforward application of Favro's work on the rotational diffusion equation (RDE), and make no contribution to the elucidation of rotational dynamics as such. A new approach is developed, a

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The rotational correlation times of the natural flavin compounds riboflavin and FMN and the flavin models lumiflavin, tetra-0-acetyl-riboflavin and their N( 3)-methylated derivatives, dissolved in water, were determined with the time-resolved fluorescence depolarization technique. Owing to the time