Anisotropic rotational diffusion of stable azoxy radicals
β Scribed by A. M. Vasserman; A. N. Kuznetsov; A. L. Kovarskii; A. L. Bulachenko
- Book ID
- 104921419
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1972
- Tongue
- English
- Weight
- 471 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0022-4766
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π SIMILAR VOLUMES
Photodissociation of tetraphenylhydrazine produces two diphenylaminyl radicals within I ps. A transient anisotropy, due to the diphenylaminyl radicals, has been measured and is described by a model based on the rotational diffusion of two initially correlated ellipsoids. A tetrahedral geometry for t
Abstrac~Analyses of the rotational diffusion characters of free and bonded nitroxyt radicals in polyvinylacetate were carried out. The radical rotational character essentially depends on the molecular sizes of the radicals. The movement of the "small" radical is matched by the arbitrary jump tumblin