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Theoretical Study of the Oxidative Addition of Ammonia to Various Unsaturated Low-Valent Transition Metal Species

✍ Scribed by Macgregor, Stuart A.

Book ID
125831936
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
233 KB
Volume
20
Category
Article
ISSN
0276-7333

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## Abstract Mild‐mannered: The low‐valent aryl gallium(I) species :GaArβ€² (Arβ€²=2,6‐(2,6‐__i__Pr~2~C~6~H~3~)~2~C~6~H~3~) undergoes addition to H~2~ or NH~3~ at room temperature and one atmosphere of pressure to afford 1 or 2 (see scheme), which were characterized by X‐ray crystallography and NMR and