Addition of Hydrogen or Ammonia to a Low
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Zhongliang Zhu; Xinping Wang; Yang Peng; Hao Lei; James C. Fettinger; Eric Rivar
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Article
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2009
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John Wiley and Sons
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English
⚖ 309 KB
## Abstract Mild‐mannered: The low‐valent aryl gallium(I) species :GaAr′ (Ar′=2,6‐(2,6‐__i__Pr~2~C~6~H~3~)~2~C~6~H~3~) undergoes addition to H~2~ or NH~3~ at room temperature and one atmosphere of pressure to afford 1 or 2 (see scheme), which were characterized by X‐ray crystallography and NMR and