Addition of Hydrogen or Ammonia to a Low-Valent Group 13 Metal Species at 25 °C and 1 Atmosphere

✍ Scribed by Zhongliang Zhu; Xinping Wang; Yang Peng; Hao Lei; James C. Fettinger; Eric Rivard; Philip P. Power

• Book ID: 101565596
• Publisher: John Wiley and Sons
• Year: 2009
• Tongue: English
• Weight: 309 KB
• Volume: 48
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.200805982

✦ Synopsis

Abstract

Mild‐mannered: The low‐valent aryl gallium(I) species :GaAr′ (Ar′=2,6‐(2,6‐__i__Pr~2~C~6~H~3~)~2~C~6~H~3~) undergoes addition to H~2~ or NH~3~ at room temperature and one atmosphere of pressure to afford 1 or 2 (see scheme), which were characterized by X‐ray crystallography and NMR and IR spectroscopy.magnified image