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Theoretical study of rearrangements in boranes

✍ Scribed by Wales, David J.; Stone, Anthony J.

Book ID
127241880
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
759 KB
Volume
26
Category
Article
ISSN
0020-1669

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## Abstract The products of the rearrangement of ethylnitrene are ethylideneimine via a 1,2 hydrogen shift, __N__‐methyl methyleneimine via a 1,2 methyl shift, and the corresponding aziridine by cyclization. The three reactions have been studied by the semiempirical MNDO method. The charge transfer