Rearrangements in icosahedral boranes and carboranes revisited
β Scribed by Christopher A. Brown; Michael L. McKee
- Publisher
- Springer-Verlag
- Year
- 2006
- Tongue
- English
- Weight
- 1003 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1610-2940
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π SIMILAR VOLUMES
Solvolysis of (o-, m-and p-carboranyl)benzyl toluene-p-sulfonates substituted at the second carbon atom with a phenyl group bearing a range of substituents at the para position has been performed. The rates of hydrolysis of m-and p-carboranyl derivatives measured linearly with increasing electron-re
The graph-theory derived model for the bonding topology in the globally delocalized polyhedral boranes B6H;-and Bl2H1:-is evaluated by comparison of the energies of the core molecular orbitals with those obtained by the 1962 LCAO-MO extended Hiickel calculations of Hoffmann and Lipscomb. Of particul