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Theoretical study of the borane and diborane positive ions

✍ Scribed by M. Sana; G. Leroy; Ch. Henriet


Publisher
Springer
Year
1989
Tongue
English
Weight
493 KB
Volume
76
Category
Article
ISSN
1432-2234

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πŸ“œ SIMILAR VOLUMES


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The electronic structure of bLs(carbonyl)diborane(4), B,H,(CO),, triborane(7) carbonyl, B3H,C0, and their parent boranes have been examined by a non-empirical molecular orbital technique. It is found that the carbonyl groups are weakly bound to the borane portion. The staggered form of B2H4(C0)2 is

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The molecular structure of the positive ions of the diatomic and triatomic systems containing the metals Cu, Ag, and Au are determined from ab initio calculations. The bond lengths of the positive diatomic ions are similar to those of the corresponding anions, because they all have a bond order of o