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Structure and stability of gold-substituted diborane, boranes, and borohydride ions

✍ Scribed by Toomas Tamm; Pekka Pyykkö

Publisher
Springer
Year
2000
Tongue
English
Weight
183 KB
Volume
103
Category
Article
ISSN
1432-2234

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The electronic structures of bis(carbony
The electronic structures of bis(carbonyl)diborane(4), triborane(7) carbonyl and their parent boranes diborane(4) and triborane(7)
✍ D.R. Armstrong 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 603 KB

The electronic structure of bLs(carbonyl)diborane(4), B,H,(CO),, triborane(7) carbonyl, B3H,C0, and their parent boranes have been examined by a non-empirical molecular orbital technique. It is found that the carbonyl groups are weakly bound to the borane portion. The staggered form of B2H4(C0)2 is