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Stability and structure of complexes of transition metal ions with nucleotides and related compounds

✍ Scribed by H Diebler

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
245 KB
Volume
79
Category
Article
ISSN
0020-1693

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Intramolecular Base Stabilization of SiN
Intramolecular Base Stabilization of SiN and SiP Compounds and Related Transition-Metal Silanediyl Complexes
✍ Prof. Dr. Robert Corriu; Dr. GΓ©rard Lanneau; Dr. Christian Priou πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 348 KB πŸ‘ 2 views

NMR values reported by Bickelhaupt et aLC4l for base-free silaphosphenes correspond to strong deshielding : 6 = + 70 to + 136 (31P NMR) and + 150 to + 200 (,'Si NMR) with high coupling constants (lJPsi = 130-150 Hz). The "Si NMR values for 3a, b are 6 = -2.7 and -6.4, respectively, corresponding to