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Intramolecular Base Stabilization of SiN and SiP Compounds and Related Transition-Metal Silanediyl Complexes

✍ Scribed by Prof. Dr. Robert Corriu; Dr. Gérard Lanneau; Dr. Christian Priou

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 348 KB
Volume: 30
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199111301

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✦ Synopsis

NMR values reported by Bickelhaupt et aLC4l for base-free silaphosphenes correspond to strong deshielding : 6 = + 70 to + 136 (31P NMR) and + 150 to + 200 (,'Si NMR) with high coupling constants (lJPsi = 130-150 Hz). The "Si NMR values for 3a, b are 6 = -2.7 and -6.4, respectively, corresponding to an expected upfield shift due to the coordi-11 30 0 VCH Verlagsgesellschaft mbH,

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