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Theoretical Studies of the Sulfenate−Sulfoxide Rearrangement

✍ Scribed by Amaudrut, Jérôme; Pasto, Daniel J.; Wiest, Olaf

Book ID
126439008
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
74 KB
Volume
63
Category
Article
ISSN
0022-3263

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✍ R.W. Hoffmann; R. Gerlach; S. Goldmann 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 207 KB

3,3lSigmatropic rearrangements follow a well defined stereochemistry') and lend themselves for asymmetric syntheses 2) . Much less is known about the stereoche-3) mistry of [2,3]sigmatropic rearrangements , which also show high stereoselecti-vities4', 5) being even stereospecific in some cases . We