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ChemInform Abstract: Theoretical Studies of the Sulfenate—Sulfoxide Rearrangement.

✍ Scribed by J. AMAUDRUT; D. J. PASTO; O. WIEST


Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
30
Category
Article
ISSN
0931-7597

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Sulfoxide Induced Sigmatropic Rearrangement (SISR) of Methyl 1-Methylsulfanylvinyl Sulfoxides. -Thiophenoxide is established as thiophilic reagent as well as base for the sequential prototropic shifts and sigmatropic rearrangement reactions of sulfoxides (I). For the SISR reaction, the conditions f