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Stereochemistry of a [2,3] sigmatropic allyl-sulfoxide/allyl sulfenate rearrangement

โœ Scribed by R.W. Hoffmann; R. Gerlach; S. Goldmann


Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
207 KB
Volume
19
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


3,3lSigmatropic rearrangements follow a well defined stereochemistry') and lend themselves for asymmetric syntheses 2) . Much less is known about the stereoche-3) mistry of [2,3]sigmatropic rearrangements , which also show high stereoselecti-vities4', 5) being even stereospecific in some cases . We were interested in


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