Theoretical studies of polyvinyl-substituted carbenium and silylenium ions
β Scribed by Truong Thanh, ; Gordon, Mark S.; Boudjouk, Philip
- Book ID
- 126141876
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 483 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
## Smnary. Gas phase basicities and ab initio MO calculations show that non-vertical stabilization by the double bond in substituted 7-norborn-Z-enyl and 7-noborna-2-dienyl cations remarkably decreases compared to the unsubstituted compounds.
The identification of the cations formed from acenaphthylene is important in the elucidation of the mechanism of its polymerisation. By improved experimental techniques and by MO calculations, some previous assignments of u.v.-vis absorptions to different ions have been corrected and new correlation