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Spectroscopic studies on carbenium ions derived from aromatic olefins—V [1–4] Experimental and theoretical studies of the cations derived from acenaphthylene

✍ Scribed by S.D. Pask; P.H. Plesch

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
318 KB
Volume
18
Category
Article
ISSN
0014-3057

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✦ Synopsis

The identification of the cations formed from acenaphthylene is important in the elucidation of the mechanism of its polymerisation. By improved experimental techniques and by MO calculations, some previous assignments of u.v.-vis absorptions to different ions have been corrected and new correlations are suggested. In particular, the absorption of the propagating acenaphthenium ion and of the ion formed by hydride abstraction from dead polymer have been identified.

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