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Experimental and theoretical studies on the homoconjugation in bicyclic carbenium and oxonium ions in the gas phase.

✍ Scribed by Raymond Houriet; Thierry Schwitzguebel; Pierre-Alain Carrupt; Pierre Vogel

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
215 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

Smnary. Gas phase basicities and ab initio MO calculations show that non-vertical stabilization by the double bond in substituted

7-norborn-Z-enyl and 7-noborna-2-dienyl cations remarkably decreases compared to the unsubstituted compounds.

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