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Theoretical Studies of Ethylene Polymerization Reactions Catalyzed by Zirconium and Titanium Chelating Alkoxide Complexes

✍ Scribed by Froese, Robert D. J.; Musaev, Djamaladdin G.; Matsubara, Toshiaki; Morokuma, Keiji


Book ID
121331630
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
255 KB
Volume
119
Category
Article
ISSN
0002-7863

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## Abstract Summary: Titanium complexes containing a triaryloxoamine ligand, [TiX{(O‐2,4‐R~2~C~6~H~2~‐6‐CH~2~)~3~N}] (R = Me, __t__Bu; X = O__i__Pr, O‐2,6‐__i__Pr~2~C~6~H~3~), exhibited notable catalytic activity for ethylene polymerization in the presence of MAO, especially at temperatures between