Theoretical studies of the Cp2ZrR+-catalyzed propylene polymerization reactions and a comparison with ethylene polymerization
β Scribed by Robert D.J Froese; Djamaladdin G Musaev; Keiji Morokuma
- Book ID
- 114143366
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 331 KB
- Volume
- 461-462
- Category
- Article
- ISSN
- 0166-1280
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π SIMILAR VOLUMES
Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit several features which differentiate them from polymerization reactions of β£-olefins: a relatively low ethylene reactivity, higher polymerization rates in the presence of β£-olefins, a high reaction order with respect to ethy
The reaction product of an incompletely desolvated ethereal Grignard reagent and TiCI,,, when employed with a trialkylaluminium cocatalyst, possesses catalytic activit~ for the polymerization of ethylene, of some two orders of magnitude (on the basis of Ti) greater than that of traditional TiCI 3 ca