## Abstract Dichlorobis(3‐hydroxy‐2‐methyl‐4‐pyrone)Zr(IV) was grafted onto different inorganic supports, namely SiO~2~, MAO‐modified SiO~2~, MCM‐41, Al~2~O~3~, and MgO. The resulting supported catalysts were shown to be active in ethylene polymerization using methylaluminoxane (MAO) as the catalys
✦ LIBER ✦
Reactivity of zirconium and titanium alkoxides bidentade complexes on ethylene polymerization
✍ Scribed by Nara R. de S. Basso; Paula P. Greco; Carlos L.P. Carone; Paolo R. Livotto; Lílian M.T. Simplício; Zênis N. da Rocha; Griselda B. Galland; João H.Z. dos Santos
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 774 KB
- Volume
- 267
- Category
- Article
- ISSN
- 1381-1169
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## Abstract Complexes (R^1^Cp)(R^2^Ind)ZrCl~2~, the catalysts previously reported active for ethylene polymerization showed high activity in ethylene/1‐hexene copolymerization and propylene polymerization in the presence of MAO. The content of 1‐hexene in copolymers ranged from 1.2% to 3.2%. In pro