𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Theoretical Prediction of the Heats of Formation of C 2 H 5 O • Radicals Derived from Ethanol and of the Kinetics of β-C−C Scission in the Ethoxy Radical

✍ Scribed by Matus, Myrna H.; Nguyen, Minh Tho; Dixon, David A.

Book ID
126259778
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
187 KB
Volume
111
Category
Article
ISSN
1089-5639

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics of the reaction: 2C2H4 → C2H5 +
Kinetics of the reaction: 2C2H4 → C2H5 + C2H3· heat of formation of the vinyl radical
✍ G. Ayranci; M. H. Back 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 929 KB

The initial rates of formation of the major products in the thermal reactions of ethylene at temperatures in the neighborhood of 800 K have been measured in the presence and absence of the additives neopentane and ethane. It has been shown that in the absence of the additive the main initiation proc

Kinetic study of the gas-phase reaction
Kinetic study of the gas-phase reaction c-C5H10 + I2 ⇄ c-C5H8 + 2HI the heat of formation of cyclopentyl radical
✍ Shozo Furuyama; David M. Golden; Sidney W. Benson 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 389 KB

The kinetics of the gas-phase dehydrogenation of cyclopentane to cyclopentene is found to be consistent with a slow attack by a n I atom (step 4, text) on cyclopentane in the range 282-382OC. The measured rate constants fit the Xrrhenius equation, log k, = 11.95 f 0.08 -(24.9 f 0.23)/0 1 mole-l sec-

Kinetic study of the gas-phase reaction
Kinetic study of the gas-phase reaction c-C5H8 + I2 ⇄ c-C5H6 + 2HI the heat of formation and the stabilization energy of the cyclopentenyl radical
✍ Shozo Furuyama; David M. Golden; Sidney W. Benson 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 276 KB 👁 1 views

The gas-phase dehydrogenation of cyclopentene to cyclopentadiene catalyzed by iodine in. the range 178-283'C has been found to obey a rate law consistent with the slow rate-determining step, I + c-C5Hs --t HI + c-C5H, , log [ka/(l moleL1 sec-')I = 10.25 \* 0.08 -(12.26 f 0.18)/0, where 0 = 2.303RT i